Coffee With D follows the story of a television journalist who succeeds in getting an interview with the dreaded underworld don D. Arnab Ghosh (Sunil Grover) is a fearless TV journalist who works for a TV channel. As the channel ratings are dipping, Arnab's boss, Mr. Roy (Rajesh Sharma), is keen that his reporters and show hosts pull up their socks. One day, Arnab comes up with the idea of interviewing the most wanted criminal, underworld D (Zakir Hussain). Since no police or media person has been able to reach D, the idea seems farfetched. But Arnab starts working on it.
Persistence pays off and Arnab is invited to interview D, he along with a crew are whisked away to a secret location to interview the underworld don, however, to keep things under his control the don sends goons to Arnab's house to hold his family hostage. Will Arnab bite the bullet and ask the tough questions? Does D answer Arnab's questions? Will D allow the interview to be telecast? Are Arnab and his family spared, is what forms the rest of the film.